JPS619942B

JPS619942B

A process for preparing an alpha -substituted cyanoacetic acid alkyl ester which comprises contacting an unsaturated nitrile of the formula I wherein R2 is a hydrogen atom or a methyl group and R3 is CH2, CHCH3, CHCN, CHC6H5 or C(CH3)2 with an alcohol of the formula ROH II wherein R is a primary, se...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: UIRUHERUMU FUOOKUTO, UE PURANGE, HERUMAN RIHITSUENHAIN, MUSUTAFUA ERU SHAHAUI
Format: Patent
Sprache:eng
Schlagworte:
ACYCLIC OR CARBOCYCLIC COMPOUNDS
APPARATUS THEREFOR
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
Online-Zugang:Volltext bestellen
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A process for preparing an alpha -substituted cyanoacetic acid alkyl ester which comprises contacting an unsaturated nitrile of the formula I wherein R2 is a hydrogen atom or a methyl group and R3 is CH2, CHCH3, CHCN, CHC6H5 or C(CH3)2 with an alcohol of the formula ROH II wherein R is a primary, secondary or tertiary saturated alkyl moiety of 1 to 20 carbon atoms and carbon monoxide in the presence of Co2(CO)8 and an alpha -substituted pyridine in the absence of hydrogen at an elevated temperature and pressure.