METHOD OF FLAMEPROOFING FREE FROM OCCURRENCE OF FORMALDEHYDE AND CAPABLE OF PROVIDING EXCELLENT WASHING FASTNESS

PURPOSE:To provide a method of flame-proofing free from occurrence of free formaldehyde and capable of providing an excellent washing fastness, by attaching a mixed aq. soln. of a diamide phosphorus nitride trimer (or tetramer) with a polyvalent amino compound to a cellulose material and heat treati...

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1. Verfasser: NOGAMI ISAO
Format: Patent
Sprache:eng
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Zusammenfassung:PURPOSE:To provide a method of flame-proofing free from occurrence of free formaldehyde and capable of providing an excellent washing fastness, by attaching a mixed aq. soln. of a diamide phosphorus nitride trimer (or tetramer) with a polyvalent amino compound to a cellulose material and heat treating the material after drying. CONSTITUTION:A mixed aq. soln. of a diamide phosphorus nitride trimer of the formula I or tetramer of the formula II with a polyvalent amino compound (urea is suitable) is attached to a cellulose material. The material is dried at a temp. of about 110 deg.C or lower and heat-treated at 160 deg.C for about 2min. The weight ratio of the diamide phosphorus nitride trimer (tetramer) to the polyvalent amino compound in the mixed aq. soln. is 3:0.1-6. The mixed aq. soln. may contain an acid catalyst (phosphoric acid is suitable), a reinforcing agent (e.g.: polyethylene higher fatty acid derivative), a softening agent and a penetrant.