MANUFACTURE OF POLYCHLOROPRENE
1. A process for the production of gel-free, toluene-soluble, sulfur-modified polychloroprene by emulsion copolymerization of chloroprene, sulfur and, optionally, other monomers copolymerizable with chloroprene and sulfur using a peroxy activator and subsequent working up by stabilization, terminati...
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Sprache: | eng |
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Zusammenfassung: | 1. A process for the production of gel-free, toluene-soluble, sulfur-modified polychloroprene by emulsion copolymerization of chloroprene, sulfur and, optionally, other monomers copolymerizable with chloroprene and sulfur using a peroxy activator and subsequent working up by stabilization, termination, degassing and isolation without separate peptization, characterized in that the polymerization is carried out in the presence of dithiocarbamates and/or xanthogenates and the activator is introduced continuously or in portions over the polymerization time. |
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