SYNTHESIS OF PRIMARY ALCOHOL MIXTURE FROM SYNTHETIC GAS UNDER PRESENCE OF CATALYST CONTAINING COPPER, COBALT, ZINC AND ALUMINUM

SYNTHESIS OF PRIMARY ALCOHOL MIXTURE FROM SYNTHETIC GAS UNDER PRESENCE OF CATALYST CONTAINING COPPER, COBALT, ZINC AND ALUMINUM

Process for manufacturing primary alcohols by reacting carbon oxides with hydrogen, in the presence of a catalyst containing, as essential elements, copper, zinc and aluminum, in respective atomic ratios of Zn/Al=0.4:1 to 2:1 Co/Al=0.2:1 to 0.75:1; Cu/Al=0.1:1 to 3:1, the proportion by weight of eac...

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Bibliographische Detailangaben
Hauptverfasser: PIEERU GURANBUARE, PATORITSUKU SHIYOOMETSUTO, FUIRITSUPU KURUTEI, KURISUCHIINU TORABUERUSU, DANIERU DEYURAN
Format: Patent
Sprache:eng
Schlagworte:
ACYCLIC OR CARBOCYCLIC COMPOUNDS
APPARATUS THEREFOR
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
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Zusammenfassung:Process for manufacturing primary alcohols by reacting carbon oxides with hydrogen, in the presence of a catalyst containing, as essential elements, copper, zinc and aluminum, in respective atomic ratios of Zn/Al=0.4:1 to 2:1 Co/Al=0.2:1 to 0.75:1; Cu/Al=0.1:1 to 3:1, the proportion by weight of each metal with respect to the total metals weight being: copper: 10-50%; cobalt: 5-25%; aluminum: 5-30%; zinc: 10-70%, the homogeneity of the catalyst being such that the variations of the atomic ratios Al/Co, Cu/Cc, Zn/Co within the catalyst, at the scale of 5 nanometers are lower than 15% with respect to the average value of said ratio. The catalyst may be prepared by complexing or by coprecipitation of the catalyst elements.