CHLOROSILANE DISPROPORTIONATION CATALYST AND DISPROPORTIONATION METHOD

PURPOSE:To obtain a chlorosilane disproportionation catalyst capable of performing disproportionation reaction with a short time even at a low temp. and high in a conversion ratio, by mixing a specific symmetric tertiary amine and hydrochloride thereof. CONSTITUTION:The titled catalyst is based on s...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Hauptverfasser:	SATOU SHINSEI, MIYAI AKIRA, NAKAJIMA MASAHIKO, ISHII MASAJI, YAMADA MITSUNORI
Format:	Patent
Sprache:	eng
Schlagworte:	CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY COMPOUNDS THEREOF INORGANIC CHEMISTRY METALLURGY NON-METALLIC ELEMENTS PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR RELEVANT APPARATUS TRANSPORTING
Online-Zugang:	Volltext bestellen
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	PURPOSE:To obtain a chlorosilane disproportionation catalyst capable of performing disproportionation reaction with a short time even at a low temp. and high in a conversion ratio, by mixing a specific symmetric tertiary amine and hydrochloride thereof. CONSTITUTION:The titled catalyst is based on symmetric tertiary amine (e.g., tri-n-butylamine) represented by formulae RRN-R and RRN-RHCl (wherein R is a 4-12C alkyl group) and hydrochloride thereof, and the ratio of hydrochloride to symmetric tertiary amine is set to 2-80mol%. That is, in disproportionating and/or re-distributing at least chlorosilane selected from trichlorosilane, dichlorosilane and monochlorosilane, the above-mentioned mixture is used in an amount of 2-50mol% to chlorosilane as a catalyst. This catalyst can perform disproportionation reaction at a low temp. of below 150 deg.C within a short time and the conversion ratio thereof can be also enhanced.