FLUORINE-CONTAINING CARBOXYLIC ACID OR ITS ESTER AND PRODUCTION THEREOF

NEW MATERIAL:A fluorine-containing carboxylic acid or ester thereof expressed by the formula [A is expressed by formula I or II (Rf is 1-11C fluoroalkyl; Rf' is CF3; R3 is CH3 or CF3; n is 1, 2 or 3); R1 and R2 are H, F, RfCH=CH or Rf'R3C=CH, at least one of R1 and R2 is expressed by formu...

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Bibliographische Detailangaben
Hauptverfasser:	MISAKI SUSUMU, TAKII KAZUHISA, KIDA YOSHIE
Format:	Patent
Sprache:	eng
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS ADHESIVES CHEMICAL PAINT OR INK REMOVERS CHEMISTRY COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS COMPOSITIONS BASED THEREON CORRECTING FLUIDS DYES FILLING PASTES INKS MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS NATURAL RESINS ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS PAINTS PASTES OR SOLIDS FOR COLOURING OR PRINTING POLISHES THEIR PREPARATION OR CHEMICAL WORKING-UP USE OF MATERIALS THEREFOR WOODSTAINS
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Beschreibung
Zusammenfassung:	NEW MATERIAL:A fluorine-containing carboxylic acid or ester thereof expressed by the formula [A is expressed by formula I or II (Rf is 1-11C fluoroalkyl; Rf' is CF3; R3 is CH3 or CF3; n is 1, 2 or 3); R1 and R2 are H, F, RfCH=CH or Rf'R3C=CH, at least one of R1 and R2 is expressed by formula III (R4 is H or lower alkyl; m is an integer 4-11)]. EXAMPLE:The compound expressed by formula IV. USE:An emulsion paint and a raw material for coating materials, plastics, fibers, surfactants or emulsifying agents having antistaining properties, etc. PREPARATION:A cyclic ketone expressed by formula V is reacted with hydrogen peroxide to form a cyclic ketone peroxide, which is then reacted with a monomer expressed by the formula RfCH=CH2 or Rf'R3C=CH2 (R3 is CH3) in the presence of a ferrous salt to afford the aimed compound expressed by the formula R1-A-R2 (R2 is CH3).