PHOSPHORIC ACID AMIDE DERIVATIVE AND INSECTICIDAL, MITICIDAL AND NEMATOCIDAL AGENT CONTAINING THE SAME

NEW MATERIAL:The compound of formula I [X is halogen, alkyl(thio), alkoxy, cyano, nitro or trifluoromethyl; Y is H or alkyl; Z and Z are O or S; R is alkyl; R is alkyl(thio), alkoxy, or phenyl; A is =CH or =N-; n is 0-4, provided that when A is =N-, n is 0-3]. EXAMPLE:O, O-Diethyl-N- 3-chloro-5- tri...

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Hauptverfasser: KOYANAGI TOORU, HAGA TAKAHIRO, YOSHIDA KIYOMITSU, TOKI TADAAKI, OKADA HIROSHI
Format: Patent
Sprache:eng
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Zusammenfassung:NEW MATERIAL:The compound of formula I [X is halogen, alkyl(thio), alkoxy, cyano, nitro or trifluoromethyl; Y is H or alkyl; Z and Z are O or S; R is alkyl; R is alkyl(thio), alkoxy, or phenyl; A is =CH or =N-; n is 0-4, provided that when A is =N-, n is 0-3]. EXAMPLE:O, O-Diethyl-N- 3-chloro-5- trifluoromethylpyridin- 2- yl -phosphoramide thioate. USE:An insecticidal, miticidal and nematocidal agent. PROCESS:The ojective compound can be prepared e.g. by reacting the compound of formula II (e.g. 2-amino-3-chloro-5-trifluoromethylpyridine) with the compound of formula III (HAL is halogen) (e.g. O,O-diethylchlorothiophosphate) in a solvent such as THF in the presence of an acid acceptor preferably at -30-+50 deg.C.