PREPARATION OF METHANOL AND FORMALDEHYDE BY PARTIAL OXIDATION OF METHANE

PURPOSE:To prepar the titled compound in high yield, by the direct catalytic partial oxidation of methane with an oxidizing agent generating oxygen anion radical, using a molybdenum oxide as a catalyst. CONSTITUTION:Methanol and formaldehyde are obtained by reacting methane with an oxidizing agent c...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Hauptverfasser:	JIYATSUKU EICHI RANSUFUOODO, IWAMOTO MASAKAZU, TOYODA SHIYUNSUKE, KAGAWA SHIYUUICHI
Format:	Patent
Sprache:	eng
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS APPARATUS THEREFOR CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION ORPROCESSING OF GOODS GENERAL METHODS OF ORGANIC CHEMISTRY GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS METALLURGY ORGANIC CHEMISTRY PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE THEIR RELEVANT APPARATUS TRANSPORTING
Online-Zugang:	Volltext bestellen
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	PURPOSE:To prepar the titled compound in high yield, by the direct catalytic partial oxidation of methane with an oxidizing agent generating oxygen anion radical, using a molybdenum oxide as a catalyst. CONSTITUTION:Methanol and formaldehyde are obtained by reacting methane with an oxidizing agent capable of easily generating oxygen anion radical, e.g. dinitrogen monoxide, nitrogen monoxide, etc. in the presence of an oxidation catalyst comprising an oxide of molybdenum. The oxidation catalyst is prepared by supporting an oxide of molybdenum on a carrier such as silica, alumina, etc. by impregnation, equilibrium adsorption, etc., drying the mixture at 100-200 deg.C, and calcining in air at 350-700 deg.C. The ratio of the molybdenum oxide (in terms of oxide) to the carrier is preferably 0.5-6wt%. The amount of the oxidizing agent is 0.05-10mol, preferably 0.5-5mol per 1mol of methane.