PREPARATION OF WATER-ABSORBIG RESIN
PURPOSE:To prepare a water-absorbing resin having high absorbing capacity to distilled water and excellent durability, and suitable as a santiary napkin, a paper diaper, a soil conditioner, etc. by neutralizing a specific carboxyl-containing polymer with an alkali metal, and crosslinking with a poly...
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Zusammenfassung: | PURPOSE:To prepare a water-absorbing resin having high absorbing capacity to distilled water and excellent durability, and suitable as a santiary napkin, a paper diaper, a soil conditioner, etc. by neutralizing a specific carboxyl-containing polymer with an alkali metal, and crosslinking with a polyvalent amine. CONSTITUTION:A maleic anhydride copolymer having an intrinsic viscosity of 0.1-8dl/g and composed of an alpha-olefin (e.g. isobuthylene) or a vinyl compound (e.g. styrene) and maleic anhydride, or a (meth)acrylic acid polymer having an intrinsic viscosity of 0.1-10dl/g[e.g. polymethyl(meth) acrylate]is neutralized with an alkali metal hydroxide (e.g. sodium hydroxide) to a neutralization degree of 0.2-0.9, and 100pts.wt. of the neutralized product thus obtained is dissolved pref. in water, added with 0.05-2pts.wt. of a polyvalent amine (e.g. polyethyleneimine), mixed, stirred, and dried to obtain the objective water-absorbing resin. |
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