PREPARATION OF POLYURETHANE POLYMER
PURPOSE:The titled polymer, obtained by reacting a blocked isocyanate compound with a compound containing an active hydrogen in the presence of a specific tin compound, phenanthroline and bipyridyl. CONSTITUTION:(A) A blocked isocyanate compound is reacted with (B) a compound containing an active hy...
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Sprache: | eng |
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Zusammenfassung: | PURPOSE:The titled polymer, obtained by reacting a blocked isocyanate compound with a compound containing an active hydrogen in the presence of a specific tin compound, phenanthroline and bipyridyl. CONSTITUTION:(A) A blocked isocyanate compound is reacted with (B) a compound containing an active hydrogen, e.g. polyether polyol, in the presence of (C) a diorganotin compound expressed by formulaIor II[R , R , R , R , R , and R are 1-8C alkyl or aryl; x is O or S; Y and Y' are -OCOR (R is H or 1-8C hydrocarbon group), aryloxy or aralkyloxy; m is 1-40; p is 0-2]and (D) 1, 10-phenanthroline or bipyridyl to give the aimed polyurethane polymer. |
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