COMPOSITION FROM OXYGENOUS PHOSPHAZENE AND TERTIARY ALCOHOL, ITS PREPARATION AND PROCESS FOR EQUILIBRATING AND/OR CONDENSING ORGANOSILICON COMPOUND

PROBLEM TO BE SOLVED: To obtain a composition which forms a catalyst having high activity of equilibrating and/or condensing an organosilicon compound simply in a manner in which the formation of free hydrogen chloride is small and controlled by mixing an oxygenous phosphazene with a tertiary alcoho...

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Hauptverfasser: DEUBZER BERNWARD DR, HERZIG CHRISTIAN DR, STALLBAUER REINHARD
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creator DEUBZER BERNWARD DR
HERZIG CHRISTIAN DR
STALLBAUER REINHARD
description PROBLEM TO BE SOLVED: To obtain a composition which forms a catalyst having high activity of equilibrating and/or condensing an organosilicon compound simply in a manner in which the formation of free hydrogen chloride is small and controlled by mixing an oxygenous phosphazene with a tertiary alcohol at a specified temperature under a specified pressure. SOLUTION: An oxygenous phosphazene is mixed with a tertiary alcohol at a temperature of 0-70 deg.C, desirably 0-20 deg.C under atmospheric pressure i.e. 900-1,100 hPa to form a composition. It is desirable that the temperature is kept 40 deg.C or below by removing the heat of reaction by a suitable cooling means. It is desirable that the reaction is carried out in an atmosphere substantially free from oxygen and water. The oxygenous phosphazene is one represented by the formula (wherein Y is chlorine or hydroxyl; and n is 0-8, desirably 1-3) or a condensate thereof. The tertiary alcohol is exemplified by tertiary butanol or dimethylpropanol. It is desirable that 1-300 ppm of this composition is used as the catalyst for equilibrating and condensing an organosilicon compound.
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SOLUTION: An oxygenous phosphazene is mixed with a tertiary alcohol at a temperature of 0-70 deg.C, desirably 0-20 deg.C under atmospheric pressure i.e. 900-1,100 hPa to form a composition. It is desirable that the temperature is kept 40 deg.C or below by removing the heat of reaction by a suitable cooling means. It is desirable that the reaction is carried out in an atmosphere substantially free from oxygen and water. The oxygenous phosphazene is one represented by the formula (wherein Y is chlorine or hydroxyl; and n is 0-8, desirably 1-3) or a condensate thereof. The tertiary alcohol is exemplified by tertiary butanol or dimethylpropanol. 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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
APPARATUS THEREFOR
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
COMPOSITIONS BASED THEREON
GENERAL METHODS OF ORGANIC CHEMISTRY
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
METALLURGY
ORGANIC CHEMISTRY
ORGANIC MACROMOLECULAR COMPOUNDS
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR PREPARATION OR CHEMICAL WORKING-UP
THEIR RELEVANT APPARATUS
TRANSPORTING
title COMPOSITION FROM OXYGENOUS PHOSPHAZENE AND TERTIARY ALCOHOL, ITS PREPARATION AND PROCESS FOR EQUILIBRATING AND/OR CONDENSING ORGANOSILICON COMPOUND
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