COMPOSITION FROM OXYGENOUS PHOSPHAZENE AND TERTIARY ALCOHOL, ITS PREPARATION AND PROCESS FOR EQUILIBRATING AND/OR CONDENSING ORGANOSILICON COMPOUND
PROBLEM TO BE SOLVED: To obtain a composition which forms a catalyst having high activity of equilibrating and/or condensing an organosilicon compound simply in a manner in which the formation of free hydrogen chloride is small and controlled by mixing an oxygenous phosphazene with a tertiary alcoho...
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creator | DEUBZER BERNWARD DR HERZIG CHRISTIAN DR STALLBAUER REINHARD |
description | PROBLEM TO BE SOLVED: To obtain a composition which forms a catalyst having high activity of equilibrating and/or condensing an organosilicon compound simply in a manner in which the formation of free hydrogen chloride is small and controlled by mixing an oxygenous phosphazene with a tertiary alcohol at a specified temperature under a specified pressure. SOLUTION: An oxygenous phosphazene is mixed with a tertiary alcohol at a temperature of 0-70 deg.C, desirably 0-20 deg.C under atmospheric pressure i.e. 900-1,100 hPa to form a composition. It is desirable that the temperature is kept 40 deg.C or below by removing the heat of reaction by a suitable cooling means. It is desirable that the reaction is carried out in an atmosphere substantially free from oxygen and water. The oxygenous phosphazene is one represented by the formula (wherein Y is chlorine or hydroxyl; and n is 0-8, desirably 1-3) or a condensate thereof. The tertiary alcohol is exemplified by tertiary butanol or dimethylpropanol. It is desirable that 1-300 ppm of this composition is used as the catalyst for equilibrating and condensing an organosilicon compound. |
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SOLUTION: An oxygenous phosphazene is mixed with a tertiary alcohol at a temperature of 0-70 deg.C, desirably 0-20 deg.C under atmospheric pressure i.e. 900-1,100 hPa to form a composition. It is desirable that the temperature is kept 40 deg.C or below by removing the heat of reaction by a suitable cooling means. It is desirable that the reaction is carried out in an atmosphere substantially free from oxygen and water. The oxygenous phosphazene is one represented by the formula (wherein Y is chlorine or hydroxyl; and n is 0-8, desirably 1-3) or a condensate thereof. The tertiary alcohol is exemplified by tertiary butanol or dimethylpropanol. It is desirable that 1-300 ppm of this composition is used as the catalyst for equilibrating and condensing an organosilicon compound.</description><edition>6</edition><language>eng</language><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS ; ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM ; APPARATUS THEREFOR ; CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY ; CHEMISTRY ; COMPOSITIONS BASED THEREON ; GENERAL METHODS OF ORGANIC CHEMISTRY ; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS ; METALLURGY ; ORGANIC CHEMISTRY ; ORGANIC MACROMOLECULAR COMPOUNDS ; PERFORMING OPERATIONS ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; THEIR PREPARATION OR CHEMICAL WORKING-UP ; THEIR RELEVANT APPARATUS ; TRANSPORTING</subject><creationdate>1998</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19981202&DB=EPODOC&CC=JP&NR=H10316756A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25543,76293</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19981202&DB=EPODOC&CC=JP&NR=H10316756A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>DEUBZER BERNWARD DR</creatorcontrib><creatorcontrib>HERZIG CHRISTIAN DR</creatorcontrib><creatorcontrib>STALLBAUER REINHARD</creatorcontrib><title>COMPOSITION FROM OXYGENOUS PHOSPHAZENE AND TERTIARY ALCOHOL, ITS PREPARATION AND PROCESS FOR EQUILIBRATING AND/OR CONDENSING ORGANOSILICON COMPOUND</title><description>PROBLEM TO BE SOLVED: To obtain a composition which forms a catalyst having high activity of equilibrating and/or condensing an organosilicon compound simply in a manner in which the formation of free hydrogen chloride is small and controlled by mixing an oxygenous phosphazene with a tertiary alcohol at a specified temperature under a specified pressure. SOLUTION: An oxygenous phosphazene is mixed with a tertiary alcohol at a temperature of 0-70 deg.C, desirably 0-20 deg.C under atmospheric pressure i.e. 900-1,100 hPa to form a composition. It is desirable that the temperature is kept 40 deg.C or below by removing the heat of reaction by a suitable cooling means. It is desirable that the reaction is carried out in an atmosphere substantially free from oxygen and water. The oxygenous phosphazene is one represented by the formula (wherein Y is chlorine or hydroxyl; and n is 0-8, desirably 1-3) or a condensate thereof. The tertiary alcohol is exemplified by tertiary butanol or dimethylpropanol. 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SOLUTION: An oxygenous phosphazene is mixed with a tertiary alcohol at a temperature of 0-70 deg.C, desirably 0-20 deg.C under atmospheric pressure i.e. 900-1,100 hPa to form a composition. It is desirable that the temperature is kept 40 deg.C or below by removing the heat of reaction by a suitable cooling means. It is desirable that the reaction is carried out in an atmosphere substantially free from oxygen and water. The oxygenous phosphazene is one represented by the formula (wherein Y is chlorine or hydroxyl; and n is 0-8, desirably 1-3) or a condensate thereof. The tertiary alcohol is exemplified by tertiary butanol or dimethylpropanol. It is desirable that 1-300 ppm of this composition is used as the catalyst for equilibrating and condensing an organosilicon compound.</abstract><edition>6</edition><oa>free_for_read</oa></addata></record> |
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subjects | ACYCLIC OR CARBOCYCLIC COMPOUNDS ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM APPARATUS THEREFOR CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY COMPOSITIONS BASED THEREON GENERAL METHODS OF ORGANIC CHEMISTRY MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR PREPARATION OR CHEMICAL WORKING-UP THEIR RELEVANT APPARATUS TRANSPORTING |
title | COMPOSITION FROM OXYGENOUS PHOSPHAZENE AND TERTIARY ALCOHOL, ITS PREPARATION AND PROCESS FOR EQUILIBRATING AND/OR CONDENSING ORGANOSILICON COMPOUND |
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