OLEFIN (CO)POLYMER COMPOSITION AND PRODUCTION THEREOF
PROBLEM TO BE SOLVED: To provide an olefin (co)polymer compsn. which has high melt tension, crystallization temp., and rigidity by producing a small amt. of a high-mol.-wt. polyolefin in advance to give a preactivated catalyst, adding a specific catalyst thereto, and conducting polymn., and to provi...
Gespeichert in:
Hauptverfasser: | , , , |
---|---|
Format: | Patent |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext bestellen |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | PROBLEM TO BE SOLVED: To provide an olefin (co)polymer compsn. which has high melt tension, crystallization temp., and rigidity by producing a small amt. of a high-mol.-wt. polyolefin in advance to give a preactivated catalyst, adding a specific catalyst thereto, and conducting polymn., and to provide a process for producing the same. SOLUTION: An olefin is (co)polymerized by using a polymn. catalyst which contains 0.01-5 pts.wt. olefin (co)polymer having an intrinsic viscosity [ηa ] (at 135 deg.C in tetralin) of 15-100 dl/g and catalyst components (A), (B), and (C), thus giving an olefin (co)polymer compsn. mainly comprising 100 pts.wt. olefin (co)polymer having an intrinsic viscosity [ηb ] (at 135 deg.C in tetralin) of 0.2-10 dl/g. Catalyst component A is a titanium trichloride compsn.; catalyst component B, an organoaluminum compd.; and catalyst component C, at least one compd. selected from among arom. carboxylic esters and organosilicon compds. each having at least either an SiOC or mercapto group. |
---|