5-METHYL-1-PHENYL-HEXANE-2,5-DICARBOXYLIC ACID DERIVATIVE, ITS PRODUCTION AND USE AS FUNGICIDE AND ITS INTERMEDIATE

PROBLEM TO BE SOLVED: To obtain the subject derivative useful as a fungicide and its intermediate. SOLUTION: This 5-methyl-1-phenyl-hexane-2,5-dicarboxylic acid derivative is shown by formula I (Q is H, an R CO or R CO; R is H or R ; R is a 1-5C alkyl; X is a halogen, a 1-5C alkyl, a 1-4C haloalkyl,...

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Hauptverfasser:	WATANABE TSUMORU, KUMAZAWA SATOSHI, HOSHI HAJIME
Format:	Patent
Sprache:	eng
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS AGRICULTURE ANIMAL HUSBANDRY BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES CHEMISTRY FISHING FORESTRY HUMAN NECESSITIES HUNTING METALLURGY ORGANIC CHEMISTRY PEST REPELLANTS OR ATTRACTANTS PLANT GROWTH REGULATORS PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTSTHEREOF TRAPPING
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Beschreibung
Zusammenfassung:	PROBLEM TO BE SOLVED: To obtain the subject derivative useful as a fungicide and its intermediate. SOLUTION: This 5-methyl-1-phenyl-hexane-2,5-dicarboxylic acid derivative is shown by formula I (Q is H, an R CO or R CO; R is H or R ; R is a 1-5C alkyl; X is a halogen, a 1-5C alkyl, a 1-4C haloalkyl, etc.) such as 1-(4- chlorophenyl)-2-(methoxycarbonyl)-5-methyl-hexane-2,5-dicarboxylic acid dimethyl ester. The compound of formula I is obtained by adding carbon monoxide to the double bond of a 1-pheny1-5-methyl-4-hexene-2-carboxylic acid derivative of formula II to carboxylate the compound and introducing the resultant substance into an ester with a 1-5C alkanol of the formula R OH. The compound of formula I shows antifungal properties by itself and is useful as an intermediate for introducing a raw material compound for an azolylmethylcyclopentanol as a fungicidal compound.