PRODUCTION OF PENTAERYTHRITOL PARTIAL (METH)ACRYLATES

PURPOSE: To readily produce the subject high-purity esters which are a liquid and each contain a large amount of partial ester derivative such as a triester derivative in high yields by reacting specific (meth)acrylic esters with aliphatic alcohols. CONSTITUTION: The transesterification of (B) penta...

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Hauptverfasser: UOHAMA MISAO, NAKAMURA KOICHI
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creator UOHAMA MISAO
NAKAMURA KOICHI
description PURPOSE: To readily produce the subject high-purity esters which are a liquid and each contain a large amount of partial ester derivative such as a triester derivative in high yields by reacting specific (meth)acrylic esters with aliphatic alcohols. CONSTITUTION: The transesterification of (B) pentaerythritol (meth)acrylates consisting essentially of (A) pentaerythritol tetra(meth)acrylate with (C) aliphatic alcohols (preferably a 1-4C aliphatic alcohol, especially methanol) is carried out in the presence of (D) a catalyst (preferably an alkali metallic hydroxide, especially potassium hydroxide). Furthermore, the content of the component (A) in the component (B) is preferably 40-100 pts.wt. based on 100 pts.wt. total amount of the component (A).
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CONSTITUTION: The transesterification of (B) pentaerythritol (meth)acrylates consisting essentially of (A) pentaerythritol tetra(meth)acrylate with (C) aliphatic alcohols (preferably a 1-4C aliphatic alcohol, especially methanol) is carried out in the presence of (D) a catalyst (preferably an alkali metallic hydroxide, especially potassium hydroxide). 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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
APPARATUS THEREFOR
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title PRODUCTION OF PENTAERYTHRITOL PARTIAL (METH)ACRYLATES
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