PRODUCTION OF POLYESTER AND COPOLYESTER

The prodn. of polyesters and copolyesters comprises (a) condensation of polyester-forming starting materials to ester or oligo-ester, followed by (b) polycondensation in presence of a Ti catalyst (I) consisting of a TiO2 ppte. and/or a TiO2/SiO2 co-ppte. with a mole ratio of TiO2:SiO2=more than 90:1...

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Bibliographische Detailangaben
Hauptverfasser: MIHIYAERU MARUTOURU, KURAUSU HAAFUERURANTO, GERURIITO OOBAARAIN, BERUNHARUTO KUUN, URURIHI BERUGAA, TOOMASU METSUGAA, BERUTORAMU BEERINGAA
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Sprache:eng
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Zusammenfassung:The prodn. of polyesters and copolyesters comprises (a) condensation of polyester-forming starting materials to ester or oligo-ester, followed by (b) polycondensation in presence of a Ti catalyst (I) consisting of a TiO2 ppte. and/or a TiO2/SiO2 co-ppte. with a mole ratio of TiO2:SiO2=more than 90:10 and/or a TiO2/ZrO2 co-ppte. with a mole ratio of TiO2:ZrO2=more than 95:5, obtd. by hydrolytic pptn. from the corresp. metal alcoholates derived from mono- or polyhydric alcohols.