PREPARATION OF TERT- BUTYL ALCOHOL FROM TERT- BUTYL HYDROPEROXIDE USING TITANIA OR ZIRCONIA

A method for preparing tertiary butyl alcohol wherein a feedstock comprising a solvent solution of tertiary butyl hydroperoxide in tertiary butyl alcohol or a mixture of tertiary butyl alcohol with isobutane is charged to a hydroperoxide decomposition reaction zone containing a catalytically effecti...

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Bibliographische Detailangaben
Hauptverfasser: JIYON RONARUDO SANDAASON, JIYON FUREDERITSUKU NAIFUTON, EDOWAADO TOOMASU MAAKISU
Format: Patent
Sprache:eng
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Beschreibung
Zusammenfassung:A method for preparing tertiary butyl alcohol wherein a feedstock comprising a solvent solution of tertiary butyl hydroperoxide in tertiary butyl alcohol or a mixture of tertiary butyl alcohol with isobutane is charged to a hydroperoxide decomposition reaction zone containing a catalytically effective amount of a hydroperoxide decomposition catalyst consisting essentially of titania or zirconia and is brought into contact with the catalyst in liquid phase under hydroperoxide decomposition reaction conditions to convert the tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol.