PREPARATION OF PENTAFLUOROETHANE (R125)

The invention relates to a method for the production of pentafluoroethane (R 125) from 1,1-dichloro-2,2,2-trifluoroethane (R 123) and hydrogen fluoride in the gas phase. In this process, a catalyst containing chromium and magnesium is used which is obtainable by precipitating chromium(III) hydroxide...

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Bibliographische Detailangaben
Hauptverfasser:	MARUTEIN SHIYOTSUTO, MARUTEIN HEFUERERU, MARUTEIN SHIYUNAUBERU
Format:	Patent
Sprache:	eng
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS APPARATUS THEREFOR CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY GENERAL METHODS OF ORGANIC CHEMISTRY METALLURGY ORGANIC CHEMISTRY PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR RELEVANT APPARATUS TRANSPORTING
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Beschreibung
Zusammenfassung:	The invention relates to a method for the production of pentafluoroethane (R 125) from 1,1-dichloro-2,2,2-trifluoroethane (R 123) and hydrogen fluoride in the gas phase. In this process, a catalyst containing chromium and magnesium is used which is obtainable by precipitating chromium(III) hydroxide by reacting 1 mol of a water-soluble chromium(III) salt with at least 1.5 mol of magnesium hydroxide or magnesium oxide in the presence of water, converting the reaction mixture into a paste which contains chromium hydroxide and a magnesium salt, and then drying the paste and treating it with hydrogen fluoride at temperatures from 20 to 500 DEG C.