PRODUCTION OF POLY(VINYLAMMONIUM FORMATE) AND AMIDINE-CONTAINING POLYMER

Amine functional polymers which are terpolymers made up of randomly linked units of amidine or amidinium formate, N-vinylformamide and either vinylamine or vinylammonium formate are prepared by aqueous hydrolysis of poly(N-vinylformamide) at a temperature in the range of 90 to 175 DEG C, preferably in the presence of a minor amount of ammonia or volatile amine. Best conversions and good control of polymer structure are obtained at 140 to 160 DEG C with a small concentration of ammonia or alkylamine. Formation of poly(vinylammonium formate) containing no other salts or ionic coproducts is realized by degassing the hydrolyzate to remove ammonia or amine from the polymer solution. The poly(vinylammonium formate) affords distinct advantages in the production of salt-free polymers by catalytic decomposition of impurities. Poly(vinylamines) containing significant amounts of amidine functionality offer advantages in applications where increased basicity is required.