JPH0586799B
NEW MATERIAL:The compound of formula I (Gal is galactose; Fruf is fructofuranose; n is 0 or 1) having the following characteristics. Molecular weight, 504 (n=0) or 666 (n=1); solubility, soluble in water and insoluble in benzene, acetone, etc.; color reaction, positive to phenol sulfuric acid method...
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Zusammenfassung: | NEW MATERIAL:The compound of formula I (Gal is galactose; Fruf is fructofuranose; n is 0 or 1) having the following characteristics. Molecular weight, 504 (n=0) or 666 (n=1); solubility, soluble in water and insoluble in benzene, acetone, etc.; color reaction, positive to phenol sulfuric acid method, etc., and negative to ninhydrin reaction, etc. EXAMPLE:beta-D-galactopyranosyl-(1 6)-beta-D-galactopyranosyl-(1 4)-D-fructofura noside of formula II. USE:A bifidus proliferation factor. PREPARATION:The oligosaccharide of formula III (Glc is glucose) used as a starting raw material is made to react with an alkali such as NaOH preferably at 20-60 deg.C for 2-10 hr to effect isomerization of the material and the reaction mixture is neutralized. After converting the unreacted oligosaccharide in the reaction mixture to an aldonic acid with a weak oxidizing agent, the reaction mixture is desalted and subjected successively to ion exchange resin treatment and activated carbon column treatment to separate the objective compound. |
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