LIQUID CRYSTAL POLYMER

Liquid-crystalline polymers having a virtually uniform molecular weight are obtainable by polymerisation of identical or different monomers of the formula I in which the variables have the following meanings: R is hydrogen, chlorine or methyl; A is a flexible, long-chain moiety which acts as a space...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser:	FUORUKAA BATSUHA, KAARU JIIMENSUMAIAA, KAARUUHAINTSU ETSUTSUBATSUHA
Format:	Patent
Sprache:	eng
Schlagworte:	ADHESIVES CHEMISTRY COMPOSITIONS BASED THEREON DEVICES OR ARRANGEMENTS, THE OPTICAL OPERATION OF WHICH ISMODIFIED BY CHANGING THE OPTICAL PROPERTIES OF THE MEDIUM OF THEDEVICES OR ARRANGEMENTS FOR THE CONTROL OF THE INTENSITY,COLOUR, PHASE, POLARISATION OR DIRECTION OF LIGHT, e.g.SWITCHING, GATING, MODULATING OR DEMODULATING DYES FREQUENCY-CHANGING MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE METALLURGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS NATURAL RESINS NON-LINEAR OPTICS OPTICAL ANALOGUE/DIGITAL CONVERTERS OPTICAL LOGIC ELEMENTS OPTICS ORGANIC MACROMOLECULAR COMPOUNDS PAINTS PHYSICS POLISHES TECHNIQUES OR PROCEDURES FOR THE OPERATION THEREOF THEIR PREPARATION OR CHEMICAL WORKING-UP
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Beschreibung
Zusammenfassung:	Liquid-crystalline polymers having a virtually uniform molecular weight are obtainable by polymerisation of identical or different monomers of the formula I in which the variables have the following meanings: R is hydrogen, chlorine or methyl; A is a flexible, long-chain moiety which acts as a spacer; B is a mesogenic moiety built up from at least two aromatic rings linked to one another in a linear or approximately linear manner; C is an optically active, chiral moiety, in 0.01 to 0.1 molar solution in an inert organic solvent in the presence of from 1 to 40 mol %, based on the monomers, of a free-radical initiator at a temperature between 40 and 60 DEG C for from 100 to 140 hours, and subsequent isolation of the polymerisation product from the reaction mixture, and the use thereof for building up recording layers for laser-optical and electrical recording elements and for electrophotography and for the construction of liquid-crystalline display elements.