HIGH-PERFORMANCE SURFACE COATING ANTISTATIC AGENT

PURPOSE:To improve the antistatic effect on synthetic resins including fluororesin and to reduce surface staining by using a specified quaternary ammonium compound as the effective component. CONSTITUTION:A compound of formula I (wherein Rf is perfluoroalkyl) obtained by reacting a lower alkyl ester...

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Bibliographische Detailangaben
Hauptverfasser: GOTO TADAO, CHIBA MASAKI, TSUKADA TOMOMICHI, NAKAMURA YOSHINOBU
Format: Patent
Sprache:eng
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Beschreibung
Zusammenfassung:PURPOSE:To improve the antistatic effect on synthetic resins including fluororesin and to reduce surface staining by using a specified quaternary ammonium compound as the effective component. CONSTITUTION:A compound of formula I (wherein Rf is perfluoroalkyl) obtained by reacting a lower alkyl ester (i) of a perfluoroalkylcarboxylic acid with dimethylaminopropylamine (ii) or a compound of formula II obtained by reacting a perfluoroalkylsulfonyl chloride (iii) formed by the electrolytic fluorination of an alkylsulfonyl chloride with a component (ii) is neutralized with an acid selected from among nitric, sulfuric, hydriodic, hydrobromic, hydrochloric, and perchloric acids, and then reacted with ethylene oxide to give the title antistatic agent comprising a quaternary ammonium compound of formula III (wherein Rf is perfluoroalkyl comprising C4F9 to C10F21; A is CONH or SO2NH; X is NO3, 1/2SO4, I, Br, Cl, ClO4 or 1/3PO4) having both a perfluoroalkyl group and a hydroxyethyl group in the molecule.