PRODUCTION OF METHACRYLIC ACID AND/OR METHACROLEIN BY CATALYTIC OXIDATION OF ISOBUTANE

PURPOSE:To obtain the aimed substance at a lower temperature in a high selectivity by using catalyst having long life containing specific heteropolyacid salt or heteropolyacid and salt of said acid in obtaining the subject substance with gas-phase catalytic oxidation of isobutane using molecular oxy...

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Hauptverfasser: NAGAI KOICHI, NAGAOKA YOSHIHIKO, SATO HIROSHI, OSU MOTOMASA
Format: Patent
Sprache:eng
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Zusammenfassung:PURPOSE:To obtain the aimed substance at a lower temperature in a high selectivity by using catalyst having long life containing specific heteropolyacid salt or heteropolyacid and salt of said acid in obtaining the subject substance with gas-phase catalytic oxidation of isobutane using molecular oxygen. CONSTITUTION:In obtaining the subject substance with gas-phase catalytic oxidation of isobutane using molecular oxygen, the aimed substance is efficiently obtained from highly concentrated isobutane (15-35mol% in raw material gas) by using a catalyst expressed by the formula (X is Ru, Cs or thallium; Y is V and/or As; Z is Cu, Ag, Bi, Fe or Co, etc.; in a case of b=12, a, c and d are respectively