ZN-FE ALLOY PLATED STEEL SHEET HAVING SUPERIOR SUITABILITY TO COATING BY ELECTRODEPOSITION
PURPOSE:To obtain a surface-treated steel sheet having superior suitability to coating by electrodeposition and superior corrosion resistance at the damaged part of a coating film by plating at least one side of a steel sheet with a Zn-Fe alloy and forming a plasma-modified layer in the surface of t...
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Zusammenfassung: | PURPOSE:To obtain a surface-treated steel sheet having superior suitability to coating by electrodeposition and superior corrosion resistance at the damaged part of a coating film by plating at least one side of a steel sheet with a Zn-Fe alloy and forming a plasma-modified layer in the surface of the resulting plating layer. CONSTITUTION:A plating layer of a Zn-Fe alloy contg. 5-30wt.% Fe is formed on at least one side of a steel sheet and this plated steel sheet 4 is set on a sample holder 5 in a vacuum chamber 2 with the plated side upward. Gaseous Ar is introduced into the chamber 2 from a gas feeding pipe 1 to form an atmosphere of Ar under reduced pressure. High voltage is then impressed between the chamber 2 as the anode and the plated steel sheet 4 as the cathode with a DC power source 7 and DC glow discharge is caused on the Zn-Fe alloy plated side or high-temp. plasma is brought into contact with the plated side to dezincify the Zn-Fe alloy plating layer. A modified Fe-Zn alloy plating layer having a very high Fe content is formed and a steel sheet for an automobile having superior suitability to coating by electrodeposition, superior corrosion resistance at the damaged part of a coating film formed by electrodeposition and superior workability is produced. |
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