JPH0144723B

PURPOSE:A stable polymer emulsion with high cationic ability, useful for paper making, civil engineering, building, etc., which is obtained by the emulsion polymerization of an ethylenically unsaturated monomer in the presence of a modified polyvinyl alcohol containing a specified copolymirizable un...

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Bibliographische Detailangaben
Hauptverfasser: SHIRAISHI MAKOTO, TANAKA TAKENORI, MORYA TAKESHI, YAMAUCHI JUNNOSUKE, MORYA TOHEI
Format: Patent
Sprache:eng
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Zusammenfassung:PURPOSE:A stable polymer emulsion with high cationic ability, useful for paper making, civil engineering, building, etc., which is obtained by the emulsion polymerization of an ethylenically unsaturated monomer in the presence of a modified polyvinyl alcohol containing a specified copolymirizable unit. CONSTITUTION:An ethylenically unsaturated monomer is smulsion-polymerized, in the presence of a modified polyvinyl alcohol containing a copolymerizable unit of formula I (wherein A is -NR R or -NR R R .X; R , R and R are a lower alkyl; X is a negative group forming a salt with an ammonium nitrogen). The copolymerizable unit of the formula I is typically N-(3-dimethylaminopropyl) methacrylamide of formula II, trimethyl(3-methacrylamidopropyl)ammonium chloride of formula III, etc. The ethylenically unsaturated monomer is vinyl acetate, a mixture of vinyl acetate and ethylene, a mixture of vinyl acetate and an acrylate, etc.