PRODUCTION OF ELECTRODE HAVING AMORPHOUS ALLOY COATING FILM

PURPOSE:To surely form an amorphous alloy coating film on the surface of an electrode by circulating a plating bath contg. an Fe family metal such as Fe, an active metal such as Cr, a salt of a metalloid such as P, an org. acid such as citric acid and a neutral salt for adjusting pH at a specified v...

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Hauptverfasser: HINO TOSHIMASA, YOSHIDA HIDEKUNI
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creator HINO TOSHIMASA
YOSHIDA HIDEKUNI
description PURPOSE:To surely form an amorphous alloy coating film on the surface of an electrode by circulating a plating bath contg. an Fe family metal such as Fe, an active metal such as Cr, a salt of a metalloid such as P, an org. acid such as citric acid and a neutral salt for adjusting pH at a specified velocity. CONSTITUTION:A plating bath contg. one or more kinds of Fe family metals selected among Fe, Ni and Co, one or more kinds of active metals selected among Cr, W and Mo, salts of one or more kinds of metalloids selected among P, S, Si and C, an org. acid such as citric acid or tartaric acid and a neutral salt for adjusting pH such as ammonium sulfate is circulated at 0.1-1.5m/sec velocity. An amorphous alloy plating film of about 3mum thickness is formed on an electrode without leaching a harmful metal from the surface of the electrode and an electrode having a service life comparable to that of a conventional Pt electrode is obtd.
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CONSTITUTION:A plating bath contg. one or more kinds of Fe family metals selected among Fe, Ni and Co, one or more kinds of active metals selected among Cr, W and Mo, salts of one or more kinds of metalloids selected among P, S, Si and C, an org. acid such as citric acid or tartaric acid and a neutral salt for adjusting pH such as ammonium sulfate is circulated at 0.1-1.5m/sec velocity. 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subjects APPARATUS THEREFOR
BASIC ELECTRIC ELEMENTS
CHEMISTRY
ELECTRICITY
ELECTROFORMING
ELECTROLYTIC OR ELECTROPHORETIC PROCESSES
ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTIONOF COMPOUNDS OR NON-METALS
METALLURGY
PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTIONOF COATINGS
PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY ORREFINING OF METALS
PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY
title PRODUCTION OF ELECTRODE HAVING AMORPHOUS ALLOY COATING FILM
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