PRODUCTION OF 4-SUBSTITUTED 3-METHYL-1-ARYL-5- AMINOPYRAZOLES

A novel process for the preparation of known 4-substituted 3-methyl-1-aryl-5-aminopyrazoles of the general formula …… in which… X , X and X independently of one another each represent halogen and… Ar represents optionally substituted phenyl. … The compounds (I) are obtained by reacting, without isol...

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description A novel process for the preparation of known 4-substituted 3-methyl-1-aryl-5-aminopyrazoles of the general formula …… in which… X , X and X independently of one another each represent halogen and… Ar represents optionally substituted phenyl. … The compounds (I) are obtained by reacting, without isolation of the intermediates, 3-ketobutyraldehyde dimethyl acetal first with amines …… then with trihalomethanesulphenyl chlorides …… then with hydroxylamine hydrochloride in the presence of an acid-binding agent and finally with arylhydrazines of the formula Ar-NH-NH2, where X , X , X and Ar have the abovementioned meanings and R and R have the meanings given in the application text. … Compounds of the formula (I) are substances having strong insecticidal activity.
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each represent halogen and… Ar represents optionally substituted phenyl. … The compounds (I) are obtained by reacting, without isolation of the intermediates, 3-ketobutyraldehyde dimethyl acetal first with amines …… then with trihalomethanesulphenyl chlorides …… then with hydroxylamine hydrochloride in the presence of an acid-binding agent and finally with arylhydrazines of the formula Ar-NH-NH2, where X , X , X and Ar have the abovementioned meanings and R and R have the meanings given in the application text. … Compounds of the formula (I) are substances having strong insecticidal activity.</description><language>eng</language><subject>AGRICULTURE ; ANIMAL HUSBANDRY ; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES ; CHEMISTRY ; FISHING ; FORESTRY ; HETEROCYCLIC COMPOUNDS ; HUMAN NECESSITIES ; HUNTING ; METALLURGY ; ORGANIC CHEMISTRY ; PEST REPELLANTS OR ATTRACTANTS ; PLANT GROWTH REGULATORS ; PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTSTHEREOF ; 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Compounds of the formula (I) are substances having strong insecticidal activity.</abstract><oa>free_for_read</oa></addata></record>
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subjects AGRICULTURE
ANIMAL HUSBANDRY
BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES
CHEMISTRY
FISHING
FORESTRY
HETEROCYCLIC COMPOUNDS
HUMAN NECESSITIES
HUNTING
METALLURGY
ORGANIC CHEMISTRY
PEST REPELLANTS OR ATTRACTANTS
PLANT GROWTH REGULATORS
PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTSTHEREOF
TRAPPING
title PRODUCTION OF 4-SUBSTITUTED 3-METHYL-1-ARYL-5- AMINOPYRAZOLES
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