PRODUCTION OF 4-SUBSTITUTED 3-METHYL-1-ARYL-5- AMINOPYRAZOLES

A novel process for the preparation of known 4-substituted 3-methyl-1-aryl-5-aminopyrazoles of the general formula …… in which… X , X and X independently of one another each represent halogen and… Ar represents optionally substituted phenyl. … The compounds (I) are obtained by reacting, without isol...

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Format: Patent
Sprache:eng
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Zusammenfassung:A novel process for the preparation of known 4-substituted 3-methyl-1-aryl-5-aminopyrazoles of the general formula …… in which… X , X and X independently of one another each represent halogen and… Ar represents optionally substituted phenyl. … The compounds (I) are obtained by reacting, without isolation of the intermediates, 3-ketobutyraldehyde dimethyl acetal first with amines …… then with trihalomethanesulphenyl chlorides …… then with hydroxylamine hydrochloride in the presence of an acid-binding agent and finally with arylhydrazines of the formula Ar-NH-NH2, where X , X , X and Ar have the abovementioned meanings and R and R have the meanings given in the application text. … Compounds of the formula (I) are substances having strong insecticidal activity.