NOVEL DOPE FOR FORMING

PURPOSE:To provide the above dope composed of a polymer consisting of a specific constitution unit and a solvent, having excellent flow birefringence, easily taking highly oriented state in molding and capable of giving a molded polyimide article having excellent heat-resistance and mechanical prope...

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Hauptverfasser: KUNUGI KATSUO, SAIKI NORITSUGU
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creator KUNUGI KATSUO
SAIKI NORITSUGU
description PURPOSE:To provide the above dope composed of a polymer consisting of a specific constitution unit and a solvent, having excellent flow birefringence, easily taking highly oriented state in molding and capable of giving a molded polyimide article having excellent heat-resistance and mechanical properties. CONSTITUTION:The objective dope is composed of (A) a polymer consisting of a constituent unit of formula (R1 and R2 are groups selected from 1-18C aliphatic hydrocarbon residue or its derivative, hydrocarbon residue containing 6-18C aromatic ring or its derivative and hydrocarbon residue containing 6-18C aliphatic ring or its derivative; R3 is at least one kind of aromatic diamine residue having chain extension bond extended coaxially or nearly coaxially or in antiparallel direction or its derivative) and (B) a solvent capable of forming a high-concentration solution of the component A having a concentration of >=10%. Preferably, the component A has an intrinsic viscosity of >=1.0 and the component B is concentrated sulfuric acid of >=98wt.% concentration or methanesulfonic acid.
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subjects AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G
APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBONFILAMENTS
CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS,THREADS, FIBRES, BRISTLES OR RIBBONS
CHEMISTRY
COMPOSITIONS BASED THEREON
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
GENERAL PROCESSES OF COMPOUNDING
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
METALLURGY
NATURAL OR ARTIFICIAL THREADS OR FIBRES
ORGANIC MACROMOLECULAR COMPOUNDS
SPINNING
TEXTILES
THEIR PREPARATION OR CHEMICAL WORKING-UP
WORKING-UP
title NOVEL DOPE FOR FORMING
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