JP2724720B

Compounds of the formula I are described [R1(FeIIR2a]q+ananX-q(I) in which a is 1 or 2, n is 1 or 2, R1 is a substituted or unsubstituted pi -arene, R2 is a substituted or unsubstituted pi -arene or cyclopentadienyl anion or indenyl anion, q is an integer from 1 to 3, and X is FSO-3 or a q-valent an...

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Hauptverfasser:	KURUTO MAIYAA, ROJAA PIEERUUERII SARUAN
Format:	Patent
Sprache:	eng
Schlagworte:	ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM ADHESIVES APPARATUS SPECIALLY ADAPTED THEREFOR CHEMICAL PAINT OR INK REMOVERS CHEMISTRY CINEMATOGRAPHY COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS COMPOSITIONS BASED THEREON COMPOSITIONS OF MACROMOLECULAR COMPOUNDS CORRECTING FLUIDS DYES ELECTROGRAPHY FILLING PASTES HOLOGRAPHY INKS MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS MATERIALS THEREFOR METALLURGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS NATURAL RESINS ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS ORIGINALS THEREFOR PAINTS PASTES OR SOLIDS FOR COLOURING OR PRINTING PHOTOGRAPHY PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES,e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTORDEVICES PHYSICS POLISHES THEIR PREPARATION OR CHEMICAL WORKING-UP USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS USE OF MATERIALS THEREFOR WOODSTAINS
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Beschreibung
Zusammenfassung:	Compounds of the formula I are described [R1(FeIIR2a]q+ananX-q(I) in which a is 1 or 2, n is 1 or 2, R1 is a substituted or unsubstituted pi -arene, R2 is a substituted or unsubstituted pi -arene or cyclopentadienyl anion or indenyl anion, q is an integer from 1 to 3, and X is FSO-3 or a q-valent anion of an organic sulfonic acid or of a carbocyclic acid; R1 can also be a polymeric, aromatic ligand. The invetion particularly relates to the compounds of the formula I wherein a is 1 and q is 1 and X-is an anion of a carbocyclic aromatic or heterocyclic aromatic sulfonic acid, selected from the group consisting of benzenesulfonic, toluenesulfonic, ethylbenzenesulfonic, isopropylbenzenesulfonic, dodecylbenzenesulfonic or dimethylbenzenesulfonic acid, 2,4,6-triisoporpylbenzenesulfonic acid, 2,4,6-trimethylbenzenesulfonic acid, naphthalenesulfonic acid, naphthalenedisulfonic acid, and naphthalenetrisulfonic acid, and the corresponding alkylated or partly fluorinated or perflourinated derivatives thereof; pyridinesulfonic, thiophenesulfonic, and pyrrolesulfonic acid and the corresponding partly fluorinated or perfluorinated derivatives of these acids. Cationically curable materials can be initiated (e.g., by irradiation or heat) in particular for the production of coatings having a good resistance to heat.