NONAQUEOUS SECONDARY BATTERY
To provide a nonaqueous secondary battery capable of suppressing an increase in battery resistance due to uneven distribution of a nonaqueous electrolytic solution inside an electrode body.SOLUTION: A nonaqueous secondary battery includes an electrode body 20 in which a positive electrode plate 21,...
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Zusammenfassung: | To provide a nonaqueous secondary battery capable of suppressing an increase in battery resistance due to uneven distribution of a nonaqueous electrolytic solution inside an electrode body.SOLUTION: A nonaqueous secondary battery includes an electrode body 20 in which a positive electrode plate 21, a negative electrode plate 24 and a separator 27 are laminated in a lamination direction, and a nonaqueous electrolytic solution. The value of E is 0.48 or more and 0.69 or less when E=A×B/(C×D) where A [mg/cm2] represents the sum of mass of a negative electrode active material included in a negative electrode mixture layer 26 per unit area on each surface of a negative electrode base material 25, B [nm3] represents an amount of lattice volume change of the negative electrode active material when the nonaqueous secondary battery is charged until a SOC is 100% from 0%, C [N] represents an amount of change of load acting on the electrode body 20 in the lamination direction when the nonaqueous secondary battery is charged until the SOC is 100% from 0%, and D [mm/kN] represents the sum of an inverse of spring constant of the positive electrode plate 21 in the lamination direction and an inverse of spring constant of the separator 27.SELECTED DRAWING: Figure 2
【課題】電極体内部における非水電解液の分布の偏りによる電池抵抗の増加を抑制可能とした非水二次電池を提供する。【解決手段】正極板21、負極板24、及びセパレータ27が積層方向に積層された電極体20と、非水電解液と、を備え、負極基材25の各面における単位面積あたりの負極合剤層26が含む負極活物質の質量の和をA〔mg/cm2〕とし、SOCが0%から100%になるまで充電したときの負極活物質の格子体積変化量をB〔nm3〕とし、SOCが0%から100%になるまで充電したときに電極体20に作用する積層方向の荷重の変化量をC〔N〕とし、積層方向における正極板21のばね定数の逆数と、セパレータ27のばね定数の逆数との和をD〔mm/kN〕とし、E=A×B/(C×D)としたときに、Eの値は、0.48以上0.69以下である。【選択図】図2 |
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