ION CONDUCTIVE OXIDE AND SECONDARY BATTERY

To provide an ion-conductive oxide having high ion conductivity.SOLUTION: An ion conductive oxide has Li or Na ion conductivity. A hexacoordinated octahedron expressed by MO6 (M is a metal element) and tetracoordinated tetrahedron expressed by XO4 (X is a metal or nonmetal element) include a structu...

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1. Verfasser: SHINREI NOBUTAKA
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Sprache:eng ; jpn
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Zusammenfassung:To provide an ion-conductive oxide having high ion conductivity.SOLUTION: An ion conductive oxide has Li or Na ion conductivity. A hexacoordinated octahedron expressed by MO6 (M is a metal element) and tetracoordinated tetrahedron expressed by XO4 (X is a metal or nonmetal element) include a structure obtained by sharing and connecting oxygen atoms; and when using bond angle O-M-O dispersion in the MO6 as a first bond angle dispersion and using bond angle O-X-O dispersion in the XO4 as a second bond angle dispersion, the ratio of the second bond angle dispersion to the first bond angle dispersion is larger than 0.15.SELECTED DRAWING: Figure 1 【課題】イオンの伝導性が高いイオン伝導性酸化物を提供する。【解決手段】実施形態に係るイオン伝導性酸化物は、LiイオンまたはNaイオンの伝導性を有するイオン伝導性酸化物であって、MO6(Mは金属元素)で表される6配位八面体と、XO4(Xは金属元素または非金属元素)で表される4配位四面体とが酸素原子を共有して連結した構造体を含み、前記MO6における結合角O-M-Oの分散を第1結合角分散とし、前記XO4における結合角O-X-Oの分散を第2結合角分散とした場合に、前記第1結合角分散に対する前記第2結合角分散の比は、0.15よりも大きい。【選択図】図1