COMPOSITE CARBON MATERIAL AND LITHIUM-ION SECONDARY BATTERY
To provide a composite carbon material for a lithium-ion secondary battery which is excellent in a low-temperature charging and discharging rate property, a high-temperature retention property, and a high-temperature cycle property and has a low internal resistance and a high coulombic efficiency.SO...
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Zusammenfassung: | To provide a composite carbon material for a lithium-ion secondary battery which is excellent in a low-temperature charging and discharging rate property, a high-temperature retention property, and a high-temperature cycle property and has a low internal resistance and a high coulombic efficiency.SOLUTION: A composite carbon material comprises a carbon material (A) and a carbonaceous coating layer (B) with which a surface of the carbon material is coated. The composite carbon material satisfies the inequality 1: 1000≤C/D≤2000. In the inequality 1, C is a hydrogen molecule (H2) amount (μmol/g) desorbed from the composite carbon material as measured in temperature-programmed desorption gas analysis (TDS) of the composite carbon material with increase in temperature from 1250°C to 1400°C and D is a carbon dioxide molecule (CO2) amount (μmol/g) desorbed from the composite carbon material as measured in the temperature-programmed desorption gas analysis (TDS) of the composite carbon material with the increase in temperature from 1250°C to 1400°C.SELECTED DRAWING: Figure 1
【課題】低温充放電レート特性、高温保存特性、高温サイクル特性に優れ、内部抵抗が低く、高クーロン効率を有するリチウムイオン二次電池のための複合炭素材料の提供。【解決手段】炭素材料(A)及びその表面を被覆する炭素性被覆層(B)を含む複合炭素材料であって、式1を満たすことを特徴とする複合炭素材料。式1:1000≦C/D≦2000。Cは、複合炭素材料に対して、1250℃から1400℃までの温度上昇における昇温脱離ガス分析(TDS)において測定された、複合炭素材料から脱離した水素分子(H2)量(μmol/g)及びDは、複合炭素材料に対して、1250℃から1400℃までの温度上昇における昇温脱離ガス分析(TDS)において測定された、複合炭素材料から脱離した二酸化炭素分子(CO2)量(μmol/g)である。【選択図】図1 |
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