OPTICAL MEMBER AND OPTICAL INSTRUMENT

To provide an optical member capable of maintaining hydrophilicity for a long period under both environments of an environment where siloxane-based contamination exists under a packaging storage state and an environment where being exposed to outdoor environment, to provide an optical instrument hav...

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description To provide an optical member capable of maintaining hydrophilicity for a long period under both environments of an environment where siloxane-based contamination exists under a packaging storage state and an environment where being exposed to outdoor environment, to provide an optical instrument having an excellent antifogging property, and to provide an optical member manufacturing method for manufacturing the optical member.SOLUTION: An optical member includes a substrate and a porous layer on the substrate. The porous layer contains silica particles, and a silanol group contained in the silica particles on a surface of the porous layer is substituted with a functional group of a divalent organic group having a specific a number of atoms and a specific hydrophilic group. In the optical member, a mole ratio of the divalent organic group relative to the silanol group on the surface of the porous layer (divalent organic group/silanol group) is in a range greater than 0.25 and not more than 1.5. An optical instrument includes the optical member. A manufacturing method of an optical member including a substrate and a porous layer on the substrate includes: a coating liquid application process; a drying and curing process; and an organic chain substitution process.SELECTED DRAWING: Figure 1 【課題】梱包保管形態におけるシロキサン系汚染物が存在する環境と屋外暴露環境のいずれにおいても長期間親水性を維持することのできる光学部材を提供する。また、防曇性に優れた光学機器を提供する。さらに、上記の光学部材を製造するための光学部材の製造方法を提供する。【解決手段】基材と、該基材上に多孔質層とを有する光学部材であって、該多孔質層がシリカ粒子を有し、該多孔質層の表面の該シリカ粒子が有するシラノール基が、特定の原子数および特定の親水基を有する2価の有機基が有する官能基により置換されており、該多孔質層の表面におけるシラノール基に対する、該2価の有機基のモル比(2価の有機基/シラノール基)が0.25より大きく1.5以下の範囲内である光学部材。前記光学部材を有する光学機器。基材と、該基材上に多孔質層とを有する光学部材の製造方法であって、塗工液塗布工程と、乾燥硬化工程と、有機鎖置換工程とを有する。【選択図】図1
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The porous layer contains silica particles, and a silanol group contained in the silica particles on a surface of the porous layer is substituted with a functional group of a divalent organic group having a specific a number of atoms and a specific hydrophilic group. In the optical member, a mole ratio of the divalent organic group relative to the silanol group on the surface of the porous layer (divalent organic group/silanol group) is in a range greater than 0.25 and not more than 1.5. An optical instrument includes the optical member. A manufacturing method of an optical member including a substrate and a porous layer on the substrate includes: a coating liquid application process; a drying and curing process; and an organic chain substitution process.SELECTED DRAWING: Figure 1 【課題】梱包保管形態におけるシロキサン系汚染物が存在する環境と屋外暴露環境のいずれにおいても長期間親水性を維持することのできる光学部材を提供する。また、防曇性に優れた光学機器を提供する。さらに、上記の光学部材を製造するための光学部材の製造方法を提供する。【解決手段】基材と、該基材上に多孔質層とを有する光学部材であって、該多孔質層がシリカ粒子を有し、該多孔質層の表面の該シリカ粒子が有するシラノール基が、特定の原子数および特定の親水基を有する2価の有機基が有する官能基により置換されており、該多孔質層の表面におけるシラノール基に対する、該2価の有機基のモル比(2価の有機基/シラノール基)が0.25より大きく1.5以下の範囲内である光学部材。前記光学部材を有する光学機器。基材と、該基材上に多孔質層とを有する光学部材の製造方法であって、塗工液塗布工程と、乾燥硬化工程と、有機鎖置換工程とを有する。【選択図】図1</description><language>eng ; jpn</language><subject>ADHESIVES ; APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL ; CHEMICAL PAINT OR INK REMOVERS ; CHEMISTRY ; COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS ; CORRECTING FLUIDS ; DYES ; FILLING PASTES ; INKS ; METALLURGY ; MISCELLANEOUS APPLICATIONS OF MATERIALS ; MISCELLANEOUS COMPOSITIONS ; NATURAL RESINS ; OPTICAL ELEMENTS, SYSTEMS, OR APPARATUS ; OPTICS ; PAINTS ; PASTES OR SOLIDS FOR COLOURING OR PRINTING ; PERFORMING OPERATIONS ; PHYSICS ; POLISHES ; PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TOSURFACES, IN GENERAL ; SPRAYING OR ATOMISING IN GENERAL ; TRANSPORTING ; USE OF MATERIALS THEREFOR ; WOODSTAINS</subject><creationdate>2020</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20200220&amp;DB=EPODOC&amp;CC=JP&amp;NR=2020027296A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,778,883,25551,76302</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20200220&amp;DB=EPODOC&amp;CC=JP&amp;NR=2020027296A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>TAKACHI MIWA</creatorcontrib><title>OPTICAL MEMBER AND OPTICAL INSTRUMENT</title><description>To provide an optical member capable of maintaining hydrophilicity for a long period under both environments of an environment where siloxane-based contamination exists under a packaging storage state and an environment where being exposed to outdoor environment, to provide an optical instrument having an excellent antifogging property, and to provide an optical member manufacturing method for manufacturing the optical member.SOLUTION: An optical member includes a substrate and a porous layer on the substrate. The porous layer contains silica particles, and a silanol group contained in the silica particles on a surface of the porous layer is substituted with a functional group of a divalent organic group having a specific a number of atoms and a specific hydrophilic group. In the optical member, a mole ratio of the divalent organic group relative to the silanol group on the surface of the porous layer (divalent organic group/silanol group) is in a range greater than 0.25 and not more than 1.5. An optical instrument includes the optical member. 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The porous layer contains silica particles, and a silanol group contained in the silica particles on a surface of the porous layer is substituted with a functional group of a divalent organic group having a specific a number of atoms and a specific hydrophilic group. In the optical member, a mole ratio of the divalent organic group relative to the silanol group on the surface of the porous layer (divalent organic group/silanol group) is in a range greater than 0.25 and not more than 1.5. An optical instrument includes the optical member. A manufacturing method of an optical member including a substrate and a porous layer on the substrate includes: a coating liquid application process; a drying and curing process; and an organic chain substitution process.SELECTED DRAWING: Figure 1 【課題】梱包保管形態におけるシロキサン系汚染物が存在する環境と屋外暴露環境のいずれにおいても長期間親水性を維持することのできる光学部材を提供する。また、防曇性に優れた光学機器を提供する。さらに、上記の光学部材を製造するための光学部材の製造方法を提供する。【解決手段】基材と、該基材上に多孔質層とを有する光学部材であって、該多孔質層がシリカ粒子を有し、該多孔質層の表面の該シリカ粒子が有するシラノール基が、特定の原子数および特定の親水基を有する2価の有機基が有する官能基により置換されており、該多孔質層の表面におけるシラノール基に対する、該2価の有機基のモル比(2価の有機基/シラノール基)が0.25より大きく1.5以下の範囲内である光学部材。前記光学部材を有する光学機器。基材と、該基材上に多孔質層とを有する光学部材の製造方法であって、塗工液塗布工程と、乾燥硬化工程と、有機鎖置換工程とを有する。【選択図】図1</abstract><oa>free_for_read</oa></addata></record>
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language eng ; jpn
recordid cdi_epo_espacenet_JP2020027296A
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subjects ADHESIVES
APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
CHEMICAL PAINT OR INK REMOVERS
CHEMISTRY
COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS
CORRECTING FLUIDS
DYES
FILLING PASTES
INKS
METALLURGY
MISCELLANEOUS APPLICATIONS OF MATERIALS
MISCELLANEOUS COMPOSITIONS
NATURAL RESINS
OPTICAL ELEMENTS, SYSTEMS, OR APPARATUS
OPTICS
PAINTS
PASTES OR SOLIDS FOR COLOURING OR PRINTING
PERFORMING OPERATIONS
PHYSICS
POLISHES
PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TOSURFACES, IN GENERAL
SPRAYING OR ATOMISING IN GENERAL
TRANSPORTING
USE OF MATERIALS THEREFOR
WOODSTAINS
title OPTICAL MEMBER AND OPTICAL INSTRUMENT
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