METHOD FOR PRODUCING BISPHENOL COMPOUND

To provide a method for producing an aldehyde bisphenol compound, wherein a 4,4'-substituted body is obtained efficiently and easily with significantly high regioselectivity.SOLUTION: When producing an aldehyde bisphenol compound from a phenol and an aldehyde, a heteropoly acid is used as an ac...

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Hauptverfasser: TAKAMI YOSHIE, NAKAMURA TAKESHI, NINOMIYA KO, KONDO MASAHIDE
Format: Patent
Sprache:eng ; jpn
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Zusammenfassung:To provide a method for producing an aldehyde bisphenol compound, wherein a 4,4'-substituted body is obtained efficiently and easily with significantly high regioselectivity.SOLUTION: When producing an aldehyde bisphenol compound from a phenol and an aldehyde, a heteropoly acid is used as an acid catalyst. The heteropoly acid has: a hydrogen atom; an oxygen atom; an atom of Groups 5 to 6 in the periodic table; and an atom of Groups 7 to 16 in the periodic table, excluding the oxygen atom, as constituent atoms, respectively, with the ratio between the number of hydrogen atoms/the number of anions being 0.080 or more.SELECTED DRAWING: None 【課題】アルデヒド型ビスフェノール化合物の製造方法において、著しく高い位置選択性で4,4'−置換体を効率的かつ容易に得る。【解決手段】フェノール類とアルデヒド類からアルデヒド型ビスフェノール化合物を製造する際に、酸触媒としてヘテロポリ酸を用いる。ヘテロポリ酸は水素原子、酸素原子、周期表第5〜6族に属する原子、および酸素原子を除く周期表第7〜16族に属する原子をそれぞれ構成原子として含み、水素数/アニオン比が0.080以上である。【選択図】なし