AQUEOUS RESIN COMPOSITION AND PRODUCTION METHOD THEREOF, AND COATING MATERIAL AND COATED ARTICLE

PROBLEM TO BE SOLVED: To provide an aqueous resin composition capable of obtaining a coating film having excellent adhesiveness to a hardly adhesive substrate such as metals and rust-prevention performance.SOLUTION: An aqueous resin composition contains a polymer P1 that contains (i) 45 mass% to 55...

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Bibliographische Detailangaben
Hauptverfasser: MAE SATOSHI, HARAGUCHI SHINSUKE
Format: Patent
Sprache:eng ; jpn
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Zusammenfassung:PROBLEM TO BE SOLVED: To provide an aqueous resin composition capable of obtaining a coating film having excellent adhesiveness to a hardly adhesive substrate such as metals and rust-prevention performance.SOLUTION: An aqueous resin composition contains a polymer P1 that contains (i) 45 mass% to 55 mass% of a constituent unit derived from alkyl (meth)acrylate a1 in which an alkyl group bound with a (meth)acryloyloxy group is an alkyl group having 4 to 22 carbons, (ii) 0.1 mass% to 5 mass% of a constituent unit derived from a radical polymerizable monomer a2 having a phosphate group, (iii) 2 mass% to 15 mass% of a constituent unit derived from a radical monomer a3 having a carbonyl group (where, alkyl(meth)acrylate and monomer a2 are excluded), and (iv) 25 mass% to 45 mass% of a constituent unit derived from a radical polymerizable monomer a4 other than the monomers a1, a2 and a3.SELECTED DRAWING: None 【課題】金属等の難密着性の基材に対する密着性及び防錆性に優れた塗膜を得ることができる水性樹脂組成物を提供する。【解決手段】(i)(メタ)アクリロイルオキシ基と結合したアルキル基が炭素数4から22のアルキル基であるアルキル(メタ)アクリレートa1由来の構成単位を45質量%以上55質量%以下、(ii)リン酸基を有するラジカル重合性単量体a2由来の構成単位を0.1質量%以上5質量%以下、(iii)カルボニル基を有するラジカル性単量体a3(ただし、アルキル(メタ)アクリレート及び単量体a2を除く)由来の構成単位を2質量%以上15質量%以下、及び(iv)前記単量体a1、a2及びa3以外のラジカル重合性単量体a4由来の構成単位を25質量%以上45質量%以下、含有する重合体P1を含む水性樹脂組成物。【選択図】 なし