COMPLEX MONOMER OF POLY ACID AND POLYMERIZABLE IMIDAZOLIUM COMPOUND
PROBLEM TO BE SOLVED: To provide a novel compound that enables materials, such as an acid catalyst, an antistatic agent, or a proton transportation agent, to be produced using various poly acids.SOLUTION: Provided is a polymerizable imidazolium salt compound represented by formula (I): ZLX. [Z is po...
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Zusammenfassung: | PROBLEM TO BE SOLVED: To provide a novel compound that enables materials, such as an acid catalyst, an antistatic agent, or a proton transportation agent, to be produced using various poly acids.SOLUTION: Provided is a polymerizable imidazolium salt compound represented by formula (I): ZLX. [Z is polymerizable imidazolium represented by formula (II); L is a monovalent or divalent alkali metal, alkaline earth metal or transition metal; X is a polyphosphoric acid represented by [MQO][M'QO], [MoO], [MoO], [VO]or [WO]; p is an integer of 1-6; q is an integer of 0-5; p+((valence of L)×q) is equal to X valence. (Ris a polymerizable substituent; Ris H, an alkyl group or an oxyalkylene group; m is an integer of 1-6; M is P, Si, Ge, Co, As, Fe, Al, Zn or B, or H; Q is W or Mo; M' is P or As; and Q' is W or Mo)].SELECTED DRAWING: None
【課題】様々なポリ酸を利用して、酸触媒、帯電防止剤、プロトン輸送剤などの素材を製造することを可能とする、新規化合物の提供。【解決手段】式(I):ZpLqXで表される、重合性イミダゾリウム塩化合物。[Zは式(II)で表される重合性イミダゾリウム;Lは、1価或いは2価のアルカリ金属、アルカリ土類金属又は遷移金属;Xは、[MQ12O40]n-[M'2Q218O62]6−、[Mo6O19]2−、[Mo8O26]4−、[V10O28]6−又は[W10O32]4−で表されるポリリン酸;pは1〜6の整数;qは0〜5の整数;p+(Lの価数×q)はXの価数に等しい(R1は重合性置換基;R2はH、アルキル基又はオキシアルキレン基;mは1〜6の整数;MはP、Si、Ge、Co、As、Fe、Al、Zn又はB或いはH2;QはW又はMo;M'はP又はAs;Q'はW又はMo)]【選択図】なし |
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