NONAQUEOUS ELECTROLYTE, AND LITHIUM-ION SECONDARY CELL AND LITHIUM-ION CAPACITOR USING THE SAME
PROBLEM TO BE SOLVED: To provide a nonaqueous electrolyte which is excellent in output characteristics and high-temperature cycle characteristics and causes little eluted metal, and a lithium-ion secondary cell and a lithium-ion capacitor containing the nonaqueous electrolyte.SOLUTION: The present i...
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Zusammenfassung: | PROBLEM TO BE SOLVED: To provide a nonaqueous electrolyte which is excellent in output characteristics and high-temperature cycle characteristics and causes little eluted metal, and a lithium-ion secondary cell and a lithium-ion capacitor containing the nonaqueous electrolyte.SOLUTION: The present invention provides: (1) a nonaqueous electrolyte where lithium hexafluorophosphate is dissolved in a nonaqueous solvent containing a cyclic carbonate and a chain carbonate, characterized by containing a C2 or greater chain ether compound that has a methoxy group and is a lithium difluorophosphate dissolution aid, where the ratio (vol%/mass%) of the proportion (vol%) of the dissolution aid to the total volume of the nonaqueous solvent to the amount (mass%) of lithium difluorophosphate in the nonaqueous electrolyte is not less than 0.1 nor more than 5, and the lithium difluorophosphate is dissolved in an amount of 1.2 mass% or more at 25°C; and (2) a lithium-ion secondary cell and a lithium-ion capacitor characterized in that the nonaqueous electrolyte is used therein.SELECTED DRAWING: None
【課題】本発明は、出力特性、高温サイクル特性に優れ、金属溶出量の少ない非水電解液、及びその非水電解液を含むリチウムイオン二次電池又はリチウムイオンキャパシタを提供する。【解決手段】(1)環状カーボネートと鎖状カーボネートとを含有する非水溶媒にヘキサフルオロリン酸リチウムが溶解されている非水電解液であって、ジフルオロリン酸リチウムの溶解助剤であるメトキシ基を有する炭素数2以上の鎖状エーテル化合物を含み、非水電解液中のジフルオロリン酸リチウムの量(質量%)に対する、非水溶媒の総体積に対する溶解助剤の割合(体積%)の比(体積%/質量%)が0.1以上5以下であり、25℃においてジフルオロリン酸リチウムが1.2質量%以上溶解していることを特徴とする非水電解液、並びに(2)前記非水電解液を用いることを特徴とするリチウムイオン二次電池及びリチウムイオンキャパシタである。【選択図】なし |
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