GLASS, GLASS MATERIAL FOR PRESS MOLDING, OPTICAL ELEMENT BLANK, AND OPTICAL ELEMENT
PROBLEM TO BE SOLVED: To provide high refractive index low dispersion fluorophosphate-based glass having excellent thermal stability, homogeneity, and acid resistance.SOLUTION: The glass comprises: as cationic components, at least P, Al, Ba, and R(Ris at least one selected from the group consisting...
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Zusammenfassung: | PROBLEM TO BE SOLVED: To provide high refractive index low dispersion fluorophosphate-based glass having excellent thermal stability, homogeneity, and acid resistance.SOLUTION: The glass comprises: as cationic components, at least P, Al, Ba, and R(Ris at least one selected from the group consisting of Mg, Ca, Sr, and Zn); and as anionic components, at least Oand F. Regarding cationic component ratios, a molar ratio of a content of Alrelative to a total content of Aland P, Al/(Al+P), is in a range of 0.56 to 0.75, a molar ratio of a content of Alrelative to a total content of Baand R, Al/(Ba+R), is 0.58 or more, a molar ratio of a total content of Baand Srrelative to a total content of Baand R, (Ba+Sr)/(Ba+R), is 0.60 or more, and a molar ratio of a total content of Li, Na, and Krelative to a total content of Aland P, (Li+Na+K)/(P+Al), is less than 0.39. The glass has a refractive index, nd, of more than 1.47 and 1.53 or less, and an Abbe number, νd, in a range of 80 to 95.SELECTED DRAWING: None
【課題】熱的安定性、均質性および耐酸性に優れる高屈折率低分散フツリン酸系ガラスを提供すること。【解決手段】カチオン成分として、P5+、Al3+、Ba2+およびR2+(R2+は、Mg2+、Ca2+、Sr2+およびZn2+からなる群から選択される一種以上)を少なくとも含み、アニオン成分として、O2−およびF−を少なくとも含み、カチオン成分比率において、Al3+およびP5+の合計含有量に対するAl3+含有量のモル比Al3+/(Al3++ P5+)は0.56〜0.75の範囲であり、Ba2+およびR2+の合計含有量に対するAl3+含有量のモル比Al3+/(Ba2++R2+)は0.58以上であり、Ba2+およびR2+の合計含有量に対するBa2+およびSr2+の合計含有量のモル比(Ba2++Sr2+)/(Ba2++R2+)は0.60以上であり、Al3+およびP3+の合計含有量に対するLi+、Na+およびK+の合計含有量のモル比(Li++Na++K+)/(P3++Al3+)は0.39未満であり、屈折率ndが1.47超1.53以下の範囲であり、かつアッベ数νdが80〜95の範囲であるガラス。【選択図】なし |
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