REGENERATION APPARATUS FOR TRIVALENT CHROMIUM PLATING SOLUTION, TRIVALENT CHROMIUM PLATING SYSTEM WITH THE REGENERATION APPARATUS, AND REGENERATION METHOD OF TRIVALENT CHROMIUM SOLUTION
PROBLEM TO BE SOLVED: To reduce concentration of hexavalent chromium ions generated in trivalent chromium plating liquid.SOLUTION: A trivalent chromium plating system comprises: a main tank 2 for applying trivalent chromium plating; a sub tank 3 which circulates trivalent chromium plating solution b...
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Zusammenfassung: | PROBLEM TO BE SOLVED: To reduce concentration of hexavalent chromium ions generated in trivalent chromium plating liquid.SOLUTION: A trivalent chromium plating system comprises: a main tank 2 for applying trivalent chromium plating; a sub tank 3 which circulates trivalent chromium plating solution between the main tank 2 and the subtank and supplies the trivalent chromium plating solution to the main tank 2; and a regeneration apparatus 4 in which the trivalent chromium plating solution in the sub tank 3 is circulated. The trivalent chromium plating solution contains trivalent chromium ions and reducing agent, the regeneration apparatus 4 comprises a regeneration tank 5 to which the trivalent chromium plating solution after trivalent chromium plating is supplied, and a cooling tank 6 to which the trivalent chromium plating solution is supplied from the regeneration tank 5. Temperature of the regeneration tank 5 is set higher than trivalent chromium plating temperature, and temperature of the cooling tank 6 is set to the trivalent chromium plating temperature or higher and lower than the temperature of the regeneration tank 5.
【課題】3価クロムめっき液中に生成する6価クロムイオン濃度を減少させる。【解決手段】3価クロムめっきを施すための本槽2と、前記本槽2との間で3価クロムめっき液を循環して前記本槽2に3価クロムめっき液を供給するためのサブ槽3と、前記サブ槽3内の3価クロムめっき液が循環される再生装置4とを備え、前記3価クロムめっき液は3価クロムイオンと還元剤とを含有し、前記再生装置4は、3価クロムめっき後の3価クロムめっき液が供給される再生槽5と、該再生槽5から3価クロムめっき液が供給される冷却槽6とを備え、前記再生槽5の温度は、3価クロムめっき温度より高く設定され、前記冷却槽6の温度は、前記3価クロムめっき温度以上であって、前記再生槽5の温度より低く設定されている。【選択図】図1 |
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