METHOD FOR FORMING PROTECTION FILM, MEMBER FOR CELL CONNECTION, AND CELL FOR SOLID OXIDE FUEL BATTERY USE

PROBLEM TO BE SOLVED: To provide a member for cell connection which has high durability, and can be used with stability over a long period of time, and to provide a cell for SOFC use.SOLUTION: A method for forming a protection film on a surface of a base material made of a Cr-containing alloy or oxi...

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Hauptverfasser: NISHIMURA SHIGEFUMI, INOUE SHUICHI, TSUKAMOTO ZENZO, SAITO TEI, NONAKA HIDEMASA, YODA MASAKAZU, TAKUWA YUYA
Format: Patent
Sprache:eng
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Zusammenfassung:PROBLEM TO BE SOLVED: To provide a member for cell connection which has high durability, and can be used with stability over a long period of time, and to provide a cell for SOFC use.SOLUTION: A method for forming a protection film on a surface of a base material made of a Cr-containing alloy or oxide and used for a cell for solid oxide fuel battery use comprises a first electro-deposition step for forming a first electro-deposition coating film by use of an anion-type resin mixture solution including, in its solid content, 30 mass% or more of metal oxide fine particles, a water-rinse step for rinsing, by water, the first electro-deposition coating film formed in the first electro-deposition step, and a second electro-deposition step for forming a second electro-deposition coating film on a surface of the first electro-deposition coating film on which water rinse has been completed, provided the above steps are conducted in this order, and a calcination step for forming calcination films composed of the first and second electro-deposition coating films with resin components lost therein by calcining the electro-deposition coating films, and a sintering step for forming a protection film including a metal oxide by sintering the calcination films.