METHOD FOR PRODUCING N-ALKENYL-SUBSTITUTED AROMATIC AMINE DERIVATIVE BY NEW OXIDATIVE AMINATION REACTION
PROBLEM TO BE SOLVED: To provide a method for producing an N-alkenyl-substituted aromatic amine derivative utilizing the new oxidative amination reaction of an olefin compound by primary aromatic amine.SOLUTION: A primary aromatic amine derivative and an olefin compound are reacted in the presence o...
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Zusammenfassung: | PROBLEM TO BE SOLVED: To provide a method for producing an N-alkenyl-substituted aromatic amine derivative utilizing the new oxidative amination reaction of an olefin compound by primary aromatic amine.SOLUTION: A primary aromatic amine derivative and an olefin compound are reacted in the presence of a Pd catalyst in an oxygen-containing atmosphere, thus oxidative amination reaction swiftly progresses only with a Pd catalyst in a catalyst amount even without adding a reoxidation agent, and an N-alkenyl-substituted aromatic amine derivative can be selectively obtained at a high yield. |
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