NEGATIVE ELECTRODE MATERIAL FOR LITHIUM ION BATTERY CONTAINING SURFACE-FLUORINATED B-TYPE TITANIUM OXIDE AND MANUFACTURING METHOD THEREOF, AND LITHIUM ION BATTERY USING THE SAME
PROBLEM TO BE SOLVED: To provide B-type titanium oxide powder which has charge and discharge characteristics and rate characteristic of B-type titanium oxide (TiO(B)) powder improved by a simple treatment and can be suitably used as a negative electrode material of a lithium ion battery.SOLUTION: B-...
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Zusammenfassung: | PROBLEM TO BE SOLVED: To provide B-type titanium oxide powder which has charge and discharge characteristics and rate characteristic of B-type titanium oxide (TiO(B)) powder improved by a simple treatment and can be suitably used as a negative electrode material of a lithium ion battery.SOLUTION: B-type titanium oxide powder is reacted at 0°C to 200°C for one minute to 10 days under fluorine-containing gas atmosphere to obtain B-type titanium oxide powder with the surface fluorinated. The fluorination treatment is preferably carried out at 0.01 atm to 2 atm. As the fluorine-containing gas, gas containing a fluorine compound selected from fluorine (F), nitrogen trifluoride (NF), methoxynitrogen trifluoride (N(CF)) and chlorine trifluoride (ClF) gases and the like is preferably used. |
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