METHOD FOR CONTINUOUSLY CARBONYLATING OLEFIN
PROBLEM TO BE SOLVED: To provide a method for continuously carbonylating olefins. SOLUTION: The method is to react an olefin with carbon monoxide and a nucleophilic compound in the presence of a catalyst system based on (a) a source of a group VIII metal cation, (b) a source of an aliphatic diphosph...
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Zusammenfassung: | PROBLEM TO BE SOLVED: To provide a method for continuously carbonylating olefins. SOLUTION: The method is to react an olefin with carbon monoxide and a nucleophilic compound in the presence of a catalyst system based on (a) a source of a group VIII metal cation, (b) a source of an aliphatic diphosphine, and (c) a carboxylic acid, i.e., a hydrocarboxylation product of the olefin, by continuously or intermittently adding the carboxylic acid during the process or continuously or intermittently adding water and producing in-situ. COPYRIGHT: (C)2009,JPO&INPIT |
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