BISIMIDAZOLINE LIGAND AND CATALYST BY USING THE SAME

PROBLEM TO BE SOLVED: To design and synthesize a bisimidazoline ligand having flexibility for aiming at the diversity of the ligand, and especially in their molecular design, to realize a useful catalytic asymmetric reaction by putting an emphasis on the design of the ligands having a high freedom....

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Hauptverfasser:	ARAI TAKAYOSHI, YANAGISAWA AKIRA, MIZUKAMI TOMOE, YOKOYAMA NAOTA
Format:	Patent
Sprache:	eng
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM APPARATUS THEREFOR CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY GENERAL METHODS OF ORGANIC CHEMISTRY HETEROCYCLIC COMPOUNDS METALLURGY ORGANIC CHEMISTRY PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR RELEVANT APPARATUS TRANSPORTING
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Beschreibung
Zusammenfassung:	PROBLEM TO BE SOLVED: To design and synthesize a bisimidazoline ligand having flexibility for aiming at the diversity of the ligand, and especially in their molecular design, to realize a useful catalytic asymmetric reaction by putting an emphasis on the design of the ligands having a high freedom. SOLUTION: This ligand is expressed by chemical formula (1) [wherein, X is any of N, C, S, P; R1, R2are each any of CH3, C2H5, -(CH2)4- and Ph; R3is H, CH3SO2, CH3C6H4SO2, C6H5SO2, CH3CO, C6H5CO, CH3, C2H5, CH2Ph and Ph; R4is any of H, CH3, C2H5, CH2Ph, Ph, CH3SO2, CH3C6H4SO2, C6H5SO2, CH3CO and C6H5CO; and provided that the Ph is an aromatic ring]. COPYRIGHT: (C)2007,JPO&INPIT