PRODUCTION OF TEREPHTHALIC ACID DIESTER AND ITS COMPOSITION

PROBLEM TO BE SOLVED: To recycle a waste polyethylene terephthalate into a resource and to obtain an ester oil comprising a terephthalic acid diester useful as a material for a lubricating oil and a plasticizer having excellent utility as a main component by transesterifying a polyethylene terephtha...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
1. Verfasser:	MIZUI KIMIYA
Format:	Patent
Sprache:	eng
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G CHEMISTRY CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATERTREATMENT OR WASTE MANAGEMENT COMPOSITIONS BASED THEREON COMPOSITIONS OF MACROMOLECULAR COMPOUNDS CRACKING HYDROCARBON OILS FUELS GENERAL PROCESSES OF COMPOUNDING GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS LUBRICANTS LUBRICATING COMPOSITIONS MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY MINERAL WAXES ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS PEAT PETROLEUM, GAS OR COKE INDUSTRIES PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS REFORMING OF NAPHTHA TECHNICAL GASES CONTAINING CARBON MONOXIDE TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE THEIR PREPARATION OR CHEMICAL WORKING-UP USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATINGINGREDIENTS IN A LUBRICATING COMPOSITION USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS WORKING-UP
Online-Zugang:	Volltext bestellen
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	PROBLEM TO BE SOLVED: To recycle a waste polyethylene terephthalate into a resource and to obtain an ester oil comprising a terephthalic acid diester useful as a material for a lubricating oil and a plasticizer having excellent utility as a main component by transesterifying a polyethylene terephthalate with an alcohol having a specific boiling point under normal pressure. SOLUTION: A polyethylene terephthalate(PET) is transesterified with a monohydric alcohol (e.g. octanol, ethylene glycol monobutyl ether, etc.), having >=170 deg.C boiling point under normal pressure to give the objective ester oil. The monohydric alcohol in an amount of 2.5 to 8 times molar amount is added to a terephthalic acid unit in the PET. Antimony trioxide may be cited a catalyst. The reaction is carried out at a reflux temperature. The oligomer content of the polyester is preferably