THERMOSETTING POLYMER, SOLUTION CONTAINING THE SAME AND FILM USING THE SOLUTION

PROBLEM TO BE SOLVED: To obtain a thermosetting polymer exhibiting excellent heat resistance, electrical characteristics, such as a low dielectric constant, and low water absorption, which are necessitated as electric and electronic materials, and useful as wiring base materials, etc., by subjecting...

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Hauptverfasser:	KITA KOHEI, TANABE TSUNEAKI
Format:	Patent
Sprache:	eng
Schlagworte:	ADHESIVES BASIC ELECTRIC ELEMENTS CHEMICAL PAINT OR INK REMOVERS CHEMISTRY COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS COMPOSITIONS BASED THEREON COMPOSITIONS OF MACROMOLECULAR COMPOUNDS CORRECTING FLUIDS DYES ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR ELECTRICITY FILLING PASTES INKS MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS NATURAL RESINS ORGANIC MACROMOLECULAR COMPOUNDS PAINTS PASTES OR SOLIDS FOR COLOURING OR PRINTING POLISHES SEMICONDUCTOR DEVICES THEIR PREPARATION OR CHEMICAL WORKING-UP USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS USE OF MATERIALS THEREFOR WOODSTAINS
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Beschreibung
Zusammenfassung:	PROBLEM TO BE SOLVED: To obtain a thermosetting polymer exhibiting excellent heat resistance, electrical characteristics, such as a low dielectric constant, and low water absorption, which are necessitated as electric and electronic materials, and useful as wiring base materials, etc., by subjecting a specific phenol and a diethynyl compound to oxidative coupling. SOLUTION: This thermosetting polymer is obtained by subjecting (A) 70-95 mol% of 2,6-diphenylphenol expressed by the formula and (B) 5-30 mol% of a diethynyl compound expressed by the formula: CH≡C-Ar-C≡CH (Ar is a divalent aromatic unit) (for example, m-diethynylbenzene) to oxidative coupling polymerization at 40-110 deg.C, and has a weight-average molecular weight of 2,000-500,000 when measured by gel permeation chromatography. The component B is added, for example, in an amount of 5-30% based on the total amount of the component A and component B. The polymerization is preferably performed in the presence of a copper compound/amine-based catalyst in a solvent, such as toluene.