MANUFACTURE OF CARBOXYLATE OF LANTHANIDE METAL, AND ITS USE AS CATALYST FOR POLYMERIZATION OF DIENIC MONOMER

PROBLEM TO BE SOLVED: To provide a method for manufacturing a carboxylate of a lanthanide metal in high yield by which the manufacturing process of the carboxylate of the lanthanide metal is simplified and the reaction time is effectively shortened. SOLUTION: The method of manufacturing a carboxylat...

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Hauptverfasser: KO SHIHO, SHU SHINAN
Format: Patent
Sprache:eng
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Zusammenfassung:PROBLEM TO BE SOLVED: To provide a method for manufacturing a carboxylate of a lanthanide metal in high yield by which the manufacturing process of the carboxylate of the lanthanide metal is simplified and the reaction time is effectively shortened. SOLUTION: The method of manufacturing a carboxylate of a lanthanide metal of the formula Ln(RCOO)3 (Ln is a lanthanide metal element having an atomic number from 57 to 71; R is a 1-19C hydrocarbon group) comprises compounding (A) a lanthanide metal (Ln) compound selected from an oxide or a carbonate of the lanthanide metal (Ln), (B) a 2-20C carboxylic acid, (C) water, and (D) an inert solvent so that the molar ratio of the water (C) to the lanthanide metal (Ln) may be larger than 5:1, and reacting them within the temperature range of 0-300 deg.C.