PRODUCTION OF PROPYLSILANE FUNCTIONALIZED AT THIRD POSITION

PROBLEM TO BE SOLVED: To provide a method for producing a propylsilane functionalized at the third position by reacting hydrogensilane with an allyl compound under the catalytic action of platinum. SOLUTION: A propylsilane functionalized at the third position is produced by the addition reaction of...

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Hauptverfasser:	PRINZ MATTHIAS, SEEBALD STEFFEN DR, KARCH RALF DR, BATZ-SOH CHRISTOPH DR
Format:	Patent
Sprache:	eng
Schlagworte:	ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM APPARATUS THEREFOR CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY GENERAL METHODS OF ORGANIC CHEMISTRY METALLURGY ORGANIC CHEMISTRY PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR RELEVANT APPARATUS TRANSPORTING
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Beschreibung
Zusammenfassung:	PROBLEM TO BE SOLVED: To provide a method for producing a propylsilane functionalized at the third position by reacting hydrogensilane with an allyl compound under the catalytic action of platinum. SOLUTION: A propylsilane functionalized at the third position is produced by the addition reaction of an allyl compound of the formula: H2C=CH-CH2X (X is Cl, Br, I, F, CN, SCN, SH, SR, OH, NRR1 or OR; R and R are each a 1-6C alkyl or a 3-7C aryl) with a silane of the formula: R2R3R4SiH [R2 to R4 are each H, a halogen, a 1-6C alkyl, a 1-6C haloalkyl, a 3-6C allyl, a 1-4C alkoxy, phenyl, an aryl or an aralkyl] at the reaction temperature of 0-200 deg.C and 800 mbar to 5 bar in the presence of a platinum catalyst having at least one kind of ligands containing sulfur.