Hydrocarbonylation or methoxycarbonylation of 1,3-diene derivatives with palladium complex

The present invention concerns a process of carbonylation of poly-unsaturated diene with high selectivity for the preparation of a ,γ-unsaturated carboxylic acid or ester in the presence of water or alcohol and catalyzed by [PdCl2P2] complex wherein P2 is two mono or one bidentate phosphine ligand.

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Bibliographische Detailangaben
Hauptverfasser: OLIVER KNOPFF, JEAN-JACQUES RIEDHAUSER
Format: Patent
Sprache:eng ; heb
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Beschreibung
Zusammenfassung:The present invention concerns a process of carbonylation of poly-unsaturated diene with high selectivity for the preparation of a ,γ-unsaturated carboxylic acid or ester in the presence of water or alcohol and catalyzed by [PdCl2P2] complex wherein P2 is two mono or one bidentate phosphine ligand.