PROCESS FOR PRODUCING SUBSTITUTED ANILINE DERIVATIVES

1. A process for the preparation of a substituted aniline of the formula see diagramm : EP0029123,P10,F1 where 1 or 2 CH groups in the aromatic ring which is free from amino groups can be replaced by nitrogen atoms, R**1, R**2 and R**3 may be identical or different and each is hydrogen, halogen, nit...

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Hauptverfasser:	HAMPRECHT,GERHARD,DE, PARG,ADOLF,DE, OESER,HEINZ-GUENTER,DE
Format:	Patent
Sprache:	eng
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS AGRICULTURE ANIMAL HUSBANDRY BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES CHEMISTRY FISHING FORESTRY HETEROCYCLIC COMPOUNDS HUMAN NECESSITIES HUNTING METALLURGY ORGANIC CHEMISTRY PEST REPELLANTS OR ATTRACTANTS PLANT GROWTH REGULATORS PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTSTHEREOF TRAPPING
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Beschreibung
Zusammenfassung:	1. A process for the preparation of a substituted aniline of the formula see diagramm : EP0029123,P10,F1 where 1 or 2 CH groups in the aromatic ring which is free from amino groups can be replaced by nitrogen atoms, R1, R2 and R3 may be identical or different and each is hydrogen, halogen, nitro, cyano, trihalomethyl, C1-4 -alkoxy, C1-4 -alkymercapto, an aliphatic radical of 1 to 4 carbon atoms an aliphatic sulfonyl radical of 1 to 4 carbon atoms, an aliphatic sulfoxide radical of 1 to 4 carbon atoms or a carbalkoxy radical of 2 to 5 carbon atoms, and Q is oxygen or sulfur, by reacting a phenolic salt with an aromatic or heterocyclic halogen compound, wherein a compound of the formula see diagramm : EP0029123,P10,F2 where Q has the above meanings and Z is a metal cation, is reacted with a haloaromatic or halo-heterocyclic compound of the formula see diagramm : EP0029123,P10,F3 where X is halogen, R1, R2 and R3 have the above meanings and 1 or 2 CH groups in the ring can be replaced by nitrogen atoms, in the presence of a crown ether as catalyst and of a polar aprotic solvent, at from 80 to 280 degrees C.